The mutual solubility of chromium and phosphorus in the solid state is probably very small. The compounds Cr3P, Cr12P7, CrP, CrP2 and CrP4 have been established reliably in the Cr-P system. CrP4 exists only at high temperatures and pressures. Data about the existence of Cr2P and Cr2P3 are controversial. In the review [90Ven, Mas] they are considered equilibrium compounds but have not been found in the latest experimental work [85Mye], which is not taken into account in the review [90Ven]. Compositional and crystal structure data of the chromium phosphides are listed in Table 1 [Mas...
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